attoPUBLICATIONS attoCATALOG-2015/16 | Page 175

Selected Application Differential Conductance Measurements on Pd Break-Junctions In this application, an attocube 4-point probe station is used to perform tunneling spectroscopy measurements in metallic nanogap devices at cryogenic temperatures. The samples consist of palladium nanowire constriction patterns on a Si/SiO2 substrate, fabricated in arrays containing between 60 and 100 devices. A single nanowire is contacted by two probes and a thermally-assisted electromigration process is employed to create a sub-nanometer tunneling gap (a). Differential conductance across the gap is measured as a function of source-drain bias. A third probe is used to contact the conducting substrate, which is used as a back gate. a Nanopositioners independently move each DC probe along the x, y, and z directions, enabling electrical contact to each device in succession. The contacting process is monitored by an inspection optics that provides good optical resolution to securely contact the pads of about 50 - 100 µm in size. b c Tunneling gaps formed with a break junction technique may be used to study a variety of complex physical phenomena, but the resulting detailed geometric configuration of the electrodes will be different for each device. Through the analysis of many samples one can extract generic features which may then be anticipated with a certain frequency of occurrence. Transport measurements in Pd break junctions reveal anomalous features in the spectrum of dI/dV vs. VSD at low temperatures (b). The sharp, bias-symmetric features undergo a rapid decrease in both amplitude and voltage position as temperature is increased, as demonstrated in the colormap (c). The associated energy of these features evolves with temperature in accord with a mean-field transition. As discussed in [1], the origin of these differential conductance features is attributed to inelastic processes involving a paramagnetic to ferromagnetic phase transition occurring at the site of the break junction tips. The accessibility of this experiment has been greatly increased by attocube’s probe station and has demonstrated how nanoscale confinement of seemingly simple materials can lead to phenomena not observable in bulk samples and macroscale thin films. [1] G . D . Scott, J . J . Palacios, and D . Natelson, ACS Nano 4, 2831-2837 (2010) attoMICROSCOPY Sophisticated Tools for Science Cutting-edge Systems PAGE 173